Oil-Impregnated Hydrocarbon-Based Polymer Films

Autor: Mukherjee, Ranit, Habibi, Mohammad, Rashed, Ziad T., Berbert, Otacilio, Shi, Xiangke, Boreyko, Jonathan B.
Přispěvatelé: Biomedical Engineering and Mechanics, Macromolecules Innovation Institute
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Scientific Reports
Scientific Reports, Vol 8, Iss 1, Pp 1-13 (2018)
ISSN: 2045-2322
Popis: Porous surfaces impregnated with a liquid lubricant exhibit minimal contact angle hysteresis with immiscible test liquids, rendering them ideal as self-cleaning materials. Rather than roughening a solid substrate, an increasingly popular choice is to use an absorbent polymer as the "porous" material. However, to date the polymer choices have been limited to expensive silicone-based polymers or complex assemblies of polymer multilayers on functionalized surfaces. In this paper, we show that hydrocarbon-based polymer films such as polyethylene can be stably impregnated with chemically compatible vegetable oils, without requiring any surface treatment. These oil-impregnated hydrocarbon-based films exhibit minimal contact angle hysteresis for a wide variety of test products including water, ketchup, and yogurt. Our oil-impregnated films remain slippery even after several weeks of being submerged in ketchup, illustrating their extreme durability. We expect that the simple and cost-effective nature of our slippery hydrocarbon-based films will make them useful for industrial packaging applications. Bemis Company, Inc. This work was supported by Bemis Company, Inc. We thank Dr. Kristi DeCourcy for technical assistance with the confocal microscopy and Prof. Robert Moore for fruitful discussions.
Databáze: OpenAIRE