Synthesis of nanoparticles in helium droplets-A characterization comparing mass-spectra and electron microscopy data

Autor: Philipp, Thaler, Alexander, Volk, Daniel, Knez, Florian, Lackner, Georg, Haberfehlner, Johannes, Steurer, Martin, Schnedlitz, Wolfgang E, Ernst
Rok vydání: 2015
Zdroj: The Journal of chemical physics. 143(13)
ISSN: 1089-7690
Popis: Micrometer sized helium droplets provide an extraordinary environment for the growth of nanoparticles. The method promises great potential for the preparation of core-shell particles as well as one-dimensional nanostructures, which agglomerate along quantum vortices, without involving solvents, ligands, or additives. Using a new apparatus, which enables us to record mass spectra of heavy dopant clusters (10(4) amu) and to produce samples for transmission electron microscopy simultaneously, we synthesize bare and bimetallic nanoparticles consisting of various materials (Au, Ni, Cr, and Ag). We present a systematical study of the growth process of clusters and nanoparticles inside the helium droplets, which can be described with a simple theoretical model.
Databáze: OpenAIRE