| Autor: |
Ibon, Alkorta, María Teresa, Benito, José, Elguero, Elisa García, Doyagüez, Monika R, Patterson, María Luisa, Jimeno, H V Rasika, Dias, Felipe, Reviriego |
| Rok vydání: |
2021 |
| Zdroj: |
Magnetic resonance in chemistry : MRCREFERENCES. 60(4) |
| ISSN: |
1097-458X |
| Popis: |
A series of DOSY experiments have been carried out to determine the solution stoichiometry of silver(I) 3,5-bis (trifluoromethyl)pyrazolate species. This compound exists as a trimer in the solid state (n = 3) but in solutions of chlorinated solvents, the DOSY data suggest the presence of a mixture of solvent stabilized monomer (n = 1) and dimer (n = 2) in equilibrium. Different approximations have been used including the Stokes-Einstein and the Stokes-Einstein-Gierer-Wirtz equations. Some methodological problems are discussed. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
Plný text