(2-Methyl-4-oxo-4H-pyran-3-olato-κO,O)bis-(triphenyl-phosphane-κP)copper(I)-triphenyl-phosphane-methanol (1/1/1)
| Autor: | Fabian M A, Muller, Theunis J, Muller, Gideon, Steyl |
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| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Structure Reports |
| ISSN: | 1600-5368 |
| Popis: | In the title compound, [Cu(C(6)H(5)O(3))(C(18)H(15)P)(2)]·C(18)H(15)P·CH(3)OH, the pyran-4-one ring is appromimately planar (r.m.s deviation = 0.0138 Å), with the Cu(I) atom 0.451 (5) Å out of the plane. The Cu(I) atom has a distorted tetra-hedral coordination. The O-Cu-O angle is 80.07 (8)° and the P-Cu-P angle is 123.49 (3)°. The crystal packing is stablized by intra-molecular C-H⋯O inter-actions and inter-molecular C-H⋯O and O-H⋯O inter-actions. |
| Databáze: | OpenAIRE |
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