Investigation on the chemiluminescence reaction of the phenylhydrazine-luminol-peroxide system

Autor:	A L S, Chandel, S A, Khan, R S, Kher, Ashish, Tiwari
Rok vydání:	2011
Předmět:	Luminescence tert-Butylhydroperoxide Luminescent Measurements Phthalic Acids Solvents Temperature Luminol Hydrogen-Ion Concentration Peroxides Phenylhydrazines
Zdroj:	Luminescence : the journal of biological and chemical luminescence. 27(6)
ISSN:	1522-7243
Popis:	We studied the chemiluminescence (CL) oxidation of phenyl hydrazine-luminol with various organic and inorganic peroxides. Maximum CL intensity for this system was obtained for t-butylhydroperoxide. The enhancement in CL depended strongly on pH and was greatest at pH 12.5. The solvent drastically enhanced the CL intensity. DMSO was found to increase the CL intensity many-fold as compared to acetonitrile and water. The effect of temperature on CL intensity has also been studied. The CL spectra revealed a broad peak at 425 nm, which suggests excited 3-aminophthalate ion as the luminophor. A mechanism to explain the reactions is suggested.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=pmid________::e45cb3be33e5fc8a4f5a369902dce80d https://pubmed.ncbi.nlm.nih.gov/22238221 Zobrazit plný text záznamu Plný text