Site-specific evolution of surface stress during the room-temperature oxidation of the Si(111)-(7 x 7) surface

Autor: N T, Kinahan, D E, Meehan, T, Narushima, S, Sachert, J J, Boland, K, Miki
Rok vydání: 2009
Zdroj: Physical review letters. 104(14)
ISSN: 1079-7114
Popis: The reaction of molecular oxygen with the Si(111)-7 x 7 surface is investigated at room temperature using in situ scanning tunneling microscopy and surface stress measurements to reveal the quantitative relationship between site-specific oxygen coverage and a decrease in tensile surface stress. This relationship is described using a modified form of the reaction model originally proposed by Dujardin et al. We show that the decrease in tensile surface stress is greatest for the faulted subunits of the 7 x 7 cell and determine the stress signatures of different reaction products, including the absence of long-lived metastable species with a unique stress signature.
Databáze: OpenAIRE