| Autor: |
Sibylle, Frieß, Anna, Benyak, Alberto, Herrera, Ana M, Escalona, Frank W, Heinemann, Jens, Langer, Dominik, Fehn, Daniel, Pividori, Alexander, Grasruck, Dominik, Munz, Karsten, Meyer, Romano, Dorta |
| Rok vydání: |
2022 |
| Zdroj: |
Inorganic chemistry. 61(3) |
| ISSN: |
1520-510X |
| Popis: |
Oxidative addition of 1.5 equiv of bromine or iodine to a Ir(I) sulfoxide pincer complex affords the corresponding Ir(IV) tris-bromido or tris-iodido complexes, respectively. The unprecedented trap-free reductive elimination of iodine from the Ir(IV)-iodido complex is induced by coordination of ligands or donor solvents. In the case of added I |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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