| Autor: |
M, Artault, N, Mokhtari, T, Cantin, A, Martin-Mingot, S, Thibaudeau |
| Rok vydání: |
2020 |
| Zdroj: |
Chemical communications (Cambridge, England). 56(44) |
| ISSN: |
1364-548X |
| Popis: |
The superacid-promoted electrophilic Csp3-H bond activation of aliphatic amines generates superelectrophilic species that can be subsequently fluorinated. Demonstrated by low-temperature in situ NMR experiments, the ammonium-carbenium dications, crucial for this reaction, can also react with C-H bonds opening future synthesis perspectives for this mode of activation. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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