Practical Synthesis of Ethynyl(phenyl)-λ

Autor: Takahiro, Hashishin, Taisei, Osawa, Kazunori, Miyamoto, Masanobu, Uchiyama
Rok vydání: 2019
Předmět:
Zdroj: Frontiers in Chemistry
ISSN: 2296-2646
Popis: Stannylation of calcium carbide followed by Sn–hypervalent iodine(III) exchange reaction cleanly afforded the electrophilic ethynylating agent ethynyl(phenyl)-λ3-iodane in high yield. This two-step method uses very inexpensive materials and is readily operable without any special precautions.
Databáze: OpenAIRE