Practical Synthesis of Ethynyl(phenyl)-λ
Autor: | Takahiro, Hashishin, Taisei, Osawa, Kazunori, Miyamoto, Masanobu, Uchiyama |
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Rok vydání: | 2019 |
Předmět: | |
Zdroj: | Frontiers in Chemistry |
ISSN: | 2296-2646 |
Popis: | Stannylation of calcium carbide followed by Sn–hypervalent iodine(III) exchange reaction cleanly afforded the electrophilic ethynylating agent ethynyl(phenyl)-λ3-iodane in high yield. This two-step method uses very inexpensive materials and is readily operable without any special precautions. |
Databáze: | OpenAIRE |
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