| Autor: |
Deepika G, Karmalkar, Virginia A, Larson, Deesha D, Malik, Yong-Min, Lee, Mi Sook, Seo, Jin, Kim, Dovydas, Vasiliauskas, Jason, Shearer, Nicolai, Lehnert, Wonwoo, Nam |
| Rok vydání: |
2022 |
| Zdroj: |
Journal of the American Chemical Society. 144(49) |
| ISSN: |
1520-5126 |
| Popis: |
High-valent first-row transition-metal-oxo complexes are important intermediates in biologically and chemically relevant oxidative transformations of organic molecules and in the water splitting reaction in (artificial) photosynthesis. While high-valent Fe- and Mn-oxo complexes have been characterized in detail, much less is known about their analogues with late transition metals. In this study, we present the synthesis and detailed characterization of a unique mononuclear terminal Ni-O complex. This compound, [Ni(TAML)(O)(OH)] |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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