| Autor: |
Sangyun, Kim, Annika D S, Richardson, Atanu, Modak, Nicholas J, Race |
| Rok vydání: |
2022 |
| Zdroj: |
The Journal of organic chemistry. |
| ISSN: |
1520-6904 |
| Popis: |
We report the dual-catalytic enantioselective allylic alkylation of 2-(pyridylmethyl)amine-derived ketimines with allylic carbonates. The reaction proceeds under mild reaction conditions to generate α-amino heteroaryl benzylamine stereocenters in good yield and enantioselectivity. Enantioselectivity is achieved through the use of a copper catalyst modified with chiral bisphosphine ligand (2 |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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