Reversible C-C bond formation: solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation
Autor: | Lee-Jon, Ball, Anthony P, Dickie, Francis S, Mair, David A, Middleton, Robin G, Pritchard |
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Rok vydání: | 2003 |
Zdroj: | Chemical communications (Cambridge, England). (6) |
ISSN: | 1359-7345 |
Popis: | Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C-C bond which ruptures upon dissolution in non-co-ordinating solvents. |
Databáze: | OpenAIRE |
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