Reversible C-C bond formation: solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation

Autor: Lee-Jon, Ball, Anthony P, Dickie, Francis S, Mair, David A, Middleton, Robin G, Pritchard
Rok vydání: 2003
Zdroj: Chemical communications (Cambridge, England). (6)
ISSN: 1359-7345
Popis: Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C-C bond which ruptures upon dissolution in non-co-ordinating solvents.
Databáze: OpenAIRE