| Autor: |
Xiang-Huan, Shan, Bo, Yang, Jian-Ping, Qu, Yan-Biao, Kang |
| Rok vydání: |
2020 |
| Předmět: |
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| Zdroj: |
Chemical communications (Cambridge, England). 56(29) |
| ISSN: |
1364-548X |
| Popis: |
In this work, CuSO4 is utilized as a practical redox catalyst for tandem dual annulation in the synthesis of indole-fused tetracyclic heteroacenes, which are important skeletons in both medicinal chemistry and materials chemistry. The preparation of such skeletons in a convenient and efficient manner is in high demand. This method realizes the modular synthesis of benzofuro-, benzothieno-, and indoloindoles from abundant feedstocks such as 2-halobenzyl halides and nitrile derivatives in up to 99% yields, providing a rapid access to diverse indole-fused heteroacenes with biological or optoelectronic properties. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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