Macromolecular Engineering of the Outer Coordination Sphere of [2Fe-2S] Metallopolymers to Enhance Catalytic Activity for H

Autor: William P, Brezinski, Metin, Karayilan, Kayla E, Clary, Keelee C, McCleary-Petersen, Liye, Fu, Krzysztof, Matyjaszewski, Dennis H, Evans, Dennis L, Lichtenberger, Richard S, Glass, Jeffrey, Pyun
Rok vydání: 2022
Zdroj: ACS macro letters. 7(11)
ISSN: 2161-1653
Popis: Small-molecule catalysts inspired by the active sites of [FeFe]-hydrogenase enzymes have long struggled to achieve fast rates of hydrogen evolution, long-term stability, water solubility, and oxygen compatibility. We profoundly improved on these deficiencies by grafting polymers from a metalloinitiator containing a [2Fe-2S] moiety to form water-soluble poly(2-dimethylamino)ethyl methacrylate metallopolymers (
Databáze: OpenAIRE