Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate

Autor:	Konrad, Swiderski, Andrew, McLean, Charles M, Gordon, D H, Vaughan
Rok vydání:	2004
Zdroj:	Chemical communications (Cambridge, England). (5)
ISSN:	1359-7345
Popis:	The bimolecular rate constant for solvent displacement, k(2), from [(C(6)H(6))Cr(CO)(2)Solv] by an incoming ligand has been determined in the room temperature ionic liquid, [bmim][PF(6)], and is compared to that for the same process in cyclohexane and dichloroethane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=pmid________::b65e1a2dd0033b6de59ab4a145dfa1b0 https://pubmed.ncbi.nlm.nih.gov/14973622 Zobrazit plný text záznamu