Triggered Gate Opening and Breathing Effects during Selective CO

Autor: Veselina M, Georgieva, Elliott L, Bruce, Maarten C, Verbraeken, Aaron R, Scott, William J, Casteel, Stefano, Brandani, Paul A, Wright
Rok vydání: 2019
Předmět:
Zdroj: Journal of the American Chemical Society. 141(32)
ISSN: 1520-5126
Popis: Zeolites with flexible structures that adapt to coordinate extraframework cations when dehydrated show a rich variety of gas adsorption behavior and can be tuned to optimize kinetics and selectivity. Merlinoite zeolite (topology type MER) with Si/Al = 3.8 has been prepared in Na, K, and Cs forms and its structural response to dehydration measured: the unit cell volumes decrease by 9.8%, 7.7%, and 7.1% for Na-, K-, and Cs-MER, respectively. Na-MER adopts
Databáze: OpenAIRE