Autor: |
Veselina M, Georgieva, Elliott L, Bruce, Maarten C, Verbraeken, Aaron R, Scott, William J, Casteel, Stefano, Brandani, Paul A, Wright |
Rok vydání: |
2019 |
Předmět: |
|
Zdroj: |
Journal of the American Chemical Society. 141(32) |
ISSN: |
1520-5126 |
Popis: |
Zeolites with flexible structures that adapt to coordinate extraframework cations when dehydrated show a rich variety of gas adsorption behavior and can be tuned to optimize kinetics and selectivity. Merlinoite zeolite (topology type MER) with Si/Al = 3.8 has been prepared in Na, K, and Cs forms and its structural response to dehydration measured: the unit cell volumes decrease by 9.8%, 7.7%, and 7.1% for Na-, K-, and Cs-MER, respectively. Na-MER adopts |
Databáze: |
OpenAIRE |
Externí odkaz: |
|