Noncovalently and covalently cross-linked polyurethane gels as alignment media and the suppression of residual polymer signals using diffusion-filtered spectroscopy

Autor: Peter, Kaden, J Christoph, Freudenberger, Burkhard, Luy
Rok vydání: 2012
Předmět:
Zdroj: Magnetic resonance in chemistry : MRC. 50
ISSN: 1097-458X
Popis: With polyurethane (PU), a novel alignment medium for organic solvents is introduced and characterized, which is very robust and easy to produce on a large scale. Linear PU already constitutes an elastomer gel with several solvents based on its ability to form hydrogen bonds. Covalent cross-linking of the polymer with accelerated electrons provides an alignment medium with different properties. However, PU exhibits a number of undesired polymer signals in corresponding spectra, which ideally have to be removed spectroscopically. Within this context, we demonstrate the applicability of diffusion-filtered experiments for removal of the polymer signals. Example spectra for the usefulness of PU alignment media are provided for the common test molecules strychnine and norcamphor.
Databáze: OpenAIRE