Surface chemistry on a polarizable surface: Coupling of CO with KTaO

Autor: Zhichang, Wang, Michele, Reticcioli, Zdenek, Jakub, Igor, Sokolović, Matthias, Meier, Lynn A, Boatner, Michael, Schmid, Gareth S, Parkinson, Ulrike, Diebold, Cesare, Franchini, Martin, Setvin
Rok vydání: 2022
Zdroj: Science advances. 8(33)
ISSN: 2375-2548
Popis: Polarizable materials attract attention in catalysis because they have a free parameter for tuning chemical reactivity. Their surfaces entangle the dielectric polarization with surface polarity, excess charge, and orbital hybridization. How this affects individual adsorbed molecules is shown for the incipient ferroelectric perovskite KTaO
Databáze: OpenAIRE