| Autor: |
Carlos, Jarava-Barrera, Alejandro, Parra, Aurora, López, Fabio, Cruz-Acosta, Daniel, Collado-Sanz, Diego J, Cárdenas, Mariola, Tortosa |
| Rok vydání: |
2015 |
| Předmět: |
|
| Zdroj: |
ACS Catalysis |
| ISSN: |
2155-5435 |
| Popis: |
In this report, we establish that DM-Segphos copper(I) complexes are efficient catalysts for the enantioselective borylation of para-quinone methides. This method provides straightforward access to chiral monobenzylic and dibenzylic boronic esters, with enantiomeric ratios up to 96:4, using a commercially available chiral phosphine. Standard manipulations of the C–B bond afford a variety of chiral diaryl derivatives. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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