| Autor: |
Matthias, Golecki, Norman, Beyer, Gunther, Steinfeld, Vasile, Lozan, Sergei, Voitekhovich, Muhamed, Sehabi, Jens, Möllmer, Hans-Jörg, Krüger, Berthold, Kersting |
| Rok vydání: |
2014 |
| Předmět: |
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| Zdroj: |
Angewandte Chemie (International ed. in English). 53(37) |
| ISSN: |
1521-3773 |
| Popis: |
The macrocyclic complex [Ni2(L)(OAc)]ClO4 (1) adsorbs up to 17 molar equivalents (270 wt%) of iodine, although it does not exhibit permanent porosity. Vibrational spectroscopic and crystallographic studies reveal that two I2 molecules are captured by means of thiophenolate→I2 charge-transfer interactions, which enable the diffusion and sorption of further I2 molecules in a polyiodide-like network. The efficient sorption and desorption characteristics make this material suitable for accommodation, sensing, and slow release of I2. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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