Perovskite-like K

Autor: Fenghua, Ding, Nenian, Charles, Jaye K, Harada, Christos D, Malliakas, Chi, Zhang, Roberto, Dos Reis, Kent J, Griffith, Matthew L, Nisbet, Weiguo, Zhang, P Shiv, Halasyamani, Vinayak P, Dravid, James M, Rondinelli, Kenneth R, Poeppelmeier
Rok vydání: 2021
Zdroj: Journal of the American Chemical Society. 143(45)
ISSN: 1520-5126
Popis: Elpasolite- and cryolite-type oxyfluorides can be regarded as superstructures of perovskite and exhibit structural diversity. While maintaining a similar structural topology with the prototype structures, changes in the size, electronegativity, and charge of cation and/or anion inevitably lead to structural evolution. Therefore, the nominal one-to-one relation suggested by a doubled formula of perovskite does not guarantee a simple 2-fold superstructure for many cases. Herein, the commensurately modulated perovskite-like K
Databáze: OpenAIRE