| Autor: |
Emily, Kiss, Craig D, Campbell, Russell W, Driver, John D, Jolliffe, Rosemary, Lang, Tetiana, Sergeieva, Sergiy, Okovytyy, Robert S, Paton, Martin D, Smith |
| Rok vydání: |
2016 |
| Předmět: |
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| Zdroj: |
Angewandte Chemie (International Ed. in English) |
| ISSN: |
1521-3773 |
| Popis: |
An approach to the intramolecular Diels–Alder reaction has led to a cascade synthesis of complex carbocycles composed of three fused rings and up to five stereocenters with complete stereocontrol. Computational analysis reveals that the reaction proceeds by a Michael/Michael/cyclopropanation/epimerization cascade in which size and coordination of the counterion is key. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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