A two-component pericyclic reaction for synthesis of substituted benzofurans and aryl-quaternary carbon bonds
| Autor: | J B, Hendrickson, M A, Walker |
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| Rok vydání: | 2000 |
| Zdroj: | Organic letters. 2(18) |
| ISSN: | 1523-7060 |
| Popis: | The reaction shown is presumed to be a new [3,3]-sigmatropic rearrangement involving an O-arylsulfoxonium species or related sulfurane. It allows a sulfoxide and a phenol to be joined and rearranged in one operation at or below room temperature, coupling an aromatic to a quaternary carbon and creating benzofurans or articulated dihydrobenzofurans in a number of examples. |
| Databáze: | OpenAIRE |
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