| Autor: |
Qi-Fa, Chen, Ze-Yu, Cheng, Rong-Zhen, Liao, Ming-Tian, Zhang |
| Rok vydání: |
2021 |
| Zdroj: |
Journal of the American Chemical Society. 143(47) |
| ISSN: |
1520-5126 |
| Popis: |
Solar-powered water splitting is a dream reaction for constructing an artificial photosynthetic system for producing solar fuels. Natural photosystem II is a prototype template for research on artificial solar energy conversion by oxidizing water into molecular oxygen and supplying four electrons for fuel production. Although a range of synthetic molecular water oxidation catalysts have been developed, the understanding of O-O bond formation in this multielectron and multiproton catalytic process is limited, and thus water oxidation is still a big challenge. Herein, we report a trinuclear copper cluster that displays outstanding reactivity toward catalytic water oxidation inspired by multicopper oxidases (MCOs), which provides efficient catalytic four-electron reduction of O |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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