| Autor: |
Jennifer C, Manton, Florian J R, Cerpentier, Emma C, Harvey, Ian P, Clark, Gregory M, Greetham, Conor, Long, Mary T, Pryce |
| Rok vydání: |
2019 |
| Zdroj: |
Dalton transactions (Cambridge, England : 2003). 48(39) |
| ISSN: |
1477-9234 |
| Popis: |
The photochemistry of (μ2-CRCR')Co2(CO)6 complexes (R = pyrenyl, R' = H; R = pyrenyl, R' = ferrocenyl; R = ferrocenyl, R = H) was investigated by ps-time-resolved infrared spectroscopy at room temperature in dichloromethane solution. The main focus of these studies was to determine the primary photoprocess relevant to the light assisted Pauson-Khand reaction. These studies were supported by spectro-electrochemical investigations and density functional calculations which suggest that the primary process to initiate the Pauson-Khand reaction involves a homolytic cleavage of the Co-Co bond forming a high-spin diradical species and not CO-loss as previously thought. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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