Ultrafast Diffusion at the Onset of Growth: O/Ru(0001)

Autor: Jack, Kelsall, Peter S M, Townsend, John, Ellis, Andrew P, Jardine, Nadav, Avidor
Rok vydání: 2020
Zdroj: Physical review letters. 126(15)
ISSN: 1079-7114
Popis: Nanoscopic clustering in a 2D disordered phase is observed for oxygen on Ru(0001) at low coverages and high temperatures. We study the coexistence of quasistatic clusters (with a characteristic length of ∼9 Å) and highly mobile atomic oxygen which diffuses between the energy-inequivalent, threefold hollow sites of the substrate. We determine a surprisingly low activation energy for diffusion of 385±20 meV. The minimum of the O-O interadsorbate potential appears to be at lower separations than previously reported.
Databáze: OpenAIRE