Crystal structure and Hirshfeld surface analysis of (3aR,4S,7S,7aS)-4,5,6,7,8,8-hexa­chloro-2-{6-[(3aR,4R,7R,7aS)-4,5,6,7,8,8-hexa­chloro-1,3-dioxo-1,3,3a,4,7,7a-hexa­hydro-2H-4,7-methano­isoindol-2-yl]hex­yl}-3a,4,7,7a-tetra­hydro-1H-4,7-methano­iso­indole-1,3(2H)-dione

Autor: Alikhanova, Aygun I., Atioğlu, Zeliha, Akkurt, Mehmet, Mlowe, Sixberth
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Acta Crystallographica Section E: Crystallographic Communications
ISSN: 2056-9890
Popis: The asymmetric unit contains one-half of the formula unit of the title compound. The crystal structure is stabilized by inter­molecular C—H⋯O, C—H⋯Cl and C—Cl⋯π inter­actions, and short inter­molecular Cl⋯O and Cl⋯Cl contacts, forming a three-dimensional network.
The mol­ecule of the title compound, C24H16Cl12N2O4, is generated by a crystallographic inversion centre at the midpoint of the central C—C bond. A kink in the mol­ecule is defined by a torsion angle of −169.86 (15)° about this central bond of the alkyl bridge. The pyrrolidine ring is essentially planar [max. deviation = 0.014 (1) Å]. The cyclo­hexane ring has a boat conformation, while both cyclo­pentane rings adopt an envelope conformation. In the crystal structure, mol­ecules are linked by inter­molecular C—H⋯O, C—H⋯Cl and C—Cl⋯π inter­actions, and short inter­molecular Cl⋯O and Cl⋯Cl contacts, forming a three-dimensional network.
Databáze: OpenAIRE