Mixed-Metal Oxo Clusters Structurally Derived from Ti6O4(OR)8(OOCR′)8

Autor: Artner, Christine, Koyun, Ayse, Czakler, Matthias, Schubert, Ulrich
Jazyk: angličtina
Rok vydání: 2014
Předmět:
Zdroj: European Journal of Inorganic Chemistry
ISSN: 1099-0682
1434-1948
Popis: The mixed-metal oxo clusters FeTi5O4(OiPr)4(OMc)10 (OMc = methacrylate), Zn2Ti4O4(OiPr)2(OMc)10, Cd4Ti2O2(OAc)2(OMc)10(HOiPr)2, [Ca2Ti4O4(OAc)2(OMc)10]n, and [Sr2Ti4O4(OMc)12(HOMc)2]n were obtained from the reaction of titanium alkoxides with the corresponding metal acetates and methacrylic acid. Their structures are derived from Ti clusters with the composition Ti6O4(OR)8(OOCR′)8. The Ca and Sr derivatives consist of chains of condensed clusters.
Databáze: OpenAIRE
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