| Autor: |
M H Jayan S, Karunarathna, Mayokun J, Ayodele, Giuseppe E, Giammanco, Alexander M, Brugh, Dayana A, Muizzi, Mariia A, Bauman, Andrew T, Torelli, Anginelle M, Alabanza, Malcolm D E, Forbes, Alexis D, Ostrowski |
| Rok vydání: |
2020 |
| Zdroj: |
Photochemicalphotobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology. 20(2) |
| ISSN: |
1474-9092 |
| Popis: |
The photochemistry of Fe(III) coordinated to natural uronate-containing polysaccharides has been investigated quantitatively in aqueous solution. It is demonstrated that the photoreduction of the coordinated Fe(III) to Fe(II) and oxidative decarboxylation occurs in a variety of uronate-containing polysaccharides. The photochemistry of the Fe(III)-polyuronic acid system generated a radical species during the reaction which was studied using the spin trapping technique. The identity of the radical species from this reaction was confirmed as CO |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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