[Synthesis of a repeating unit and the dimer of the repeating unit of the major chain of Shigella flexneri O-antigen polysaccharide]

Autor: Iu E, Tsvetkov, N E, Baĭramova, L V, Bakinovskiĭ, N K, Kochetkov, N F, Iankina
Rok vydání: 1986
Předmět:
Zdroj: Bioorganicheskaia khimiia. 12(9)
ISSN: 0132-3423
Popis: Methyl glycoside of the tetrasaccharide GlcNAc(beta 1-2)Rha(alpha 1-2)Rha(alpha 1-3)Rha, which represents a repeating unit of the basic chain of Shigella flexneri O-antigenic polysaccharides, was synthesized using acylated monosaccharide synthons. A dimer of the repeating unit, octasaccharide [GlcNAc(beta 1-2)Rha(alpha 1-2) Rha(alpha 1-3)Rha(alpha 1-3)]2-OMe was obtained by TrClO4-catalyzed condensation of two tetrasaccharide blocks.
Databáze: OpenAIRE