| Autor: |
Daniela, Mazzier, Dario, Mosconi, Giulia, Marafon, Aikebaier, Reheman, Claudio, Toniolo, Alessandro, Moretto |
| Rok vydání: |
2016 |
| Předmět: |
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| Zdroj: |
Journal of peptide science : an official publication of the European Peptide Society. 23(2) |
| ISSN: |
1099-1387 |
| Popis: |
A symmetrical dipeptide-based diacetylene system (DAs) was found to be able to self-assemble in dichloromethane and to form a compact fiber network which resulted in a stable organogel. As a consequence of the organogel formation, we explored the possibility to run a light-induced topochemical polymerization. This is a typical reaction of ordered diacetylene moieties taking advantage from their organized packing mode resulting from fiber formation. Evidence for the generation of peptide-based polydiacetylenes is provided by Raman, UV-Vis, and CD spectroscopies and a set of microscopic techniques. Finally, we succeeded in processing a polymeric composite by use of the electrospinning technique, starting from a mixture of a dipeptide-based diacetylene and polymethyl methacrylate. Copyright © 2016 European Peptide Society and John WileySons, Ltd. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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