Mn-NHC Electrocatalysts: Increasing π Acidity Lowers the Reduction Potential and Increases the Turnover Frequency for CO

Autor: Charles J, Stanton, Jonathon E, Vandezande, George F, Majetich, Henry F, Schaefer, Jay, Agarwal
Rok vydání: 2016
Zdroj: Inorganic chemistry. 55(19)
ISSN: 1520-510X
Popis: A new manganese(I) N-heterocyclic carbene electrocatalyst containing a benzimidazole-pyrimidine-based ligand is reported for the two-electron conversion of CO
Databáze: OpenAIRE