Synthesis of the cyclobutanone core of solanoeclepin A intramolecular allene butenolide photocycloaddition

Autor: Bui T B, Hue, Jan, Dijkink, Sanne, Kuiper, Kimberly K, Larson, Frank S, Guziec, Kees, Goubitz, Jan, Fraanje, Henk, Schenk, Jan H, van Maarseveen, Henk, Hiemstra
Rok vydání: 2003
Předmět:
Zdroj: Organicbiomolecular chemistry. 1(24)
ISSN: 1477-0520
Popis: The compact tricyclic substructure of solanoeclepin A containing the cyclobutanone ring was prepared by using as the key step a highly regioselective intramolecular [2 + 2]-photocycloaddition reaction between one of the [small pi]-bonds of an allene and the CC double bond of a butenolide.
Databáze: OpenAIRE