| Autor: |
Daniel, Prochowicz, Iwona, Justyniak, Arkadiusz, Kornowicz, Tomasz, Kaczorowski, Zbigniew, Kaszkur, Janusz, Lewiński |
| Rok vydání: |
2012 |
| Zdroj: |
Chemistry (Weinheim an der Bergstrasse, Germany). 18(24) |
| ISSN: |
1521-3765 |
| Popis: |
The polymer network: The reaction of quinine (QN) with CuI under solvothermal, as well as liquid-assisted grinding, conditions afforded a unique 1D homochiral coordination polymer {[Cu(4)(μ(3)-I)(4)(QN)(2)][Cu(3)(μ(3)-I)(2)(μ(2)-I)(QN)(2)](2)}(n), containing both triangular Cu(3)I(3) and cubane Cu(4)I(4) clusters as connecting nodes (see scheme). Van der Waals interactions between the adjacent 1D polymer chains lead to an extended quasi-honeycomb homochiral pillared 3D network with solvent-free 1D channels. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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