| Autor: |
Thomas, Salomon, José L, Doménech, Philipp C, Schmid, Ernest A, Michael, Stephan, Schlemmer, Oskar, Asvany |
| Rok vydání: |
2021 |
| Předmět: |
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| Zdroj: |
J Mol Spectrosc |
| ISSN: |
0022-2852 |
| Popis: |
A cryogenic 22-pole ion trap apparatus is used in combination with a table-top pulsed IR source to probe weakly bound CH(+)-He and CH(+)-He(4) complexes by predissociation spectroscopy at 4 K. The infrared photodissociation spectra of the C–H stretching vibrations are recorded in the range of 2720–2800 cm(−1). The spectrum of CH(+)-He exhibits perpendicular transitions of a near prolate top with a band origin at 2745.9 cm(−1), and thus confirms it to have a T-shaped structure. For CH(+)-He(4), the C-H stretch along the symmetry axis of this oblate top results in parallel transitions. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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