Supramolecular D⋯A-layered structures based on germanium complexes with 2,3-dihydroxynaphthalene and

Autor: Pavel G, Shangin, Irina V, Krylova, Andrey V, Lalov, Anna Y, Kozmenkova, Evgeniya A, Saverina, Petr A, Buikin, Alexander A, Korlyukov, Alyona A, Starikova, Elena N, Nikolaevskaya, Mikhail P, Egorov, Mikhail A, Syroeshkin
Rok vydání: 2021
Zdroj: RSC advances. 11(35)
ISSN: 2046-2069
Popis: The concept of using redox-active ligands, which has become extremely widespread in organometallic chemistry, is often considered from 'their effect on the metal center properties' point of view and 'how to modify the ligands'. In this paper, we present the reverse side of this effective approach - a dramatic change of redox properties of ligands under the influence of a redox-inert metal. Germanium derivatives based on 2,3-dihydroxynaphthalene (1) and
Databáze: OpenAIRE