| Autor: |
Kazuhiro, Uemura, Yuya, Ikeda, Atsushi, Takamori, Tomoyuki, Takeyama, Satoshi, Iwatsuki |
| Rok vydání: |
2022 |
| Zdroj: |
Chemistry (Weinheim an der Bergstrasse, Germany). |
| ISSN: |
1521-3765 |
| Popis: |
Heterometallic extended metal atom chains (EMACs) aligned with three types of metals were rationally synthesized by forming unbridged metal-metal bonds based on the interactions between highest and lowest unoccupied molecular orbitals at the dz2 orbital. These chains form pentanuclear structures aligned as Rh-Pt-M-Pt-Rh with relatively large formation constants of 5.0 × 1013 M-2 for M = Pt and 6.3 × 1011 M-2 for M = Pd, while retaining their backbones in solution. In the case of M = Cu, the original Cu(+2) atoms were reduced to be Cu(+1) during the synthetic process. Cu(+1) has an unprecedented trigonal bipyramidal coordination geometry. The reported synthesis based on asymmetrical dinuclear complexes provides a guideline for the synthesis of hetero-EMACs to allow several analogs via judicious combinations realized by tuning the number of metal nuclei and metal species. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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