A Novel Class of Ruthenium Catalysts for Olefin Metathesis

Autor: Thomas, Weskamp, Wolfgang C, Schattenmann, Michael, Spiegler, Wolfgang A, Herrmann
Rok vydání: 1998
Zdroj: Angewandte Chemie (International ed. in English). 37(18)
ISSN: 1521-3773
Popis: The different nature of carbene ligands is clearly demonstrated by the first ruthenium-based complexes 1, which contain both alkylidene and N-heterocyclic carbene moieties. The latter exhibit a pronounced Lewis base behavior. Moreover, this difference forms the basis of the high catalytic activities of these compounds in olefin metathesis reactions.
Databáze: OpenAIRE