Spin State Tunes Oxygen Atom Transfer towards Fe

Autor: Carmen E, Castillo, Ilaria, Gamba, Laia, Vicens, Martin, Clémancey, Jean-Marc, Latour, Miquel, Costas, Manuel G, Basallote
Rok vydání: 2020
Zdroj: Chemistry (Weinheim an der Bergstrasse, Germany). 27(15)
ISSN: 1521-3765
Popis: Oxoiron(IV) complexes bearing tetradentate ligands have been extensively studied as models for the active oxidants in non-heme iron-dependent enzymes. These species are commonly generated by oxidation of their ferrous precursors. The mechanisms of these reactions have seldom been investigated. In this work, the reaction kinetics of complexes [Fe
Databáze: OpenAIRE