Popis: |
The interaction of succinic acid dihydrazide with Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) was investigated in aqueous medium at 303K and ionic strength of 0.1 mol dm-3. The speciation and stability constants of the metal complexes formed were determined by pH-metric method. Mononuclear and homo binuclear species in different protonation and deprotonation states were identified, the corresponding formation constants calculated using MINIQUAD-75 computer program, and species distribution diagrams produced using the HYSS computer program. Selection of the best-fit chemical models was based on statistical parameters. |