| Autor: |
Catherine A, Slinn, Alison J, Redgrave, S Lucy, Hind, Chris, Edlin, Steven P, Nolan, Veronique, Gouverneur |
| Rok vydání: |
2003 |
| Zdroj: |
Organicbiomolecular chemistry. 1(21) |
| ISSN: |
1477-0520 |
| Popis: |
Ru- and Mo-based catalysts can be used in ring closing metathesis (RCM) reactions to synthesise cyclic phosphines protected as their borane complexes. The compatibility of the Schrock Mo-catalyst and the N-heterocyclic carbene Ru-catalysts with this class of substrates is particularly noteworthy as asymmetric RCM (ARCM) is now emerging as a new tool for the preparation of homochiral phosphines. One of the key results is that the Mo-catalyst allows the ring closure of the unprotected diallylphenylphosphine with 95% conversion. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
