[Study on preparations and fluorescent properties of rare earth complex with property of fluorescence sensor]

Autor: Dong-Liang, Tao, Hui-Zhen, Li, Yu-Min, Cui, Ya-Li, Jia, Shao-Xuan, Liu, Yi-Zhuang, Xu, Yong-Zhong, Wang, Ji-Tang, Chen, Rui-Juan, Shi, Wen-Bao, Zhang, Xue-Ling, Qiao, Wen-Zhong, Sun, Hong, Zhang
Rok vydání: 2012
Zdroj: Guang pu xue yu guang pu fen xi = Guang pu. 32(9)
ISSN: 1000-0593
Popis: Europium chloride, 2-thienylformyltrifluoroacetone and sodium silicate were used to synthesize new-style rare earth complex (Eu-TNS). By adding into dichloromethane solution containing Eu-TNS, the fluorescent intensities were enhanced gradually and regularly. High-resolution mass spectrometry was used to detect the formula of Eu-TNS, which belongs to multi-core rare-earth complex. Polarity of solution increasing by adding absolute ethanol will cause Eu-TNS to dissociate, which enhances the fluoresceot intensities of Eu-TNS solution. This rare earth complex Eu-TNS can be employed as fluorescence sensor to detect the content of ethanol in organic solvent.
Databáze: OpenAIRE