[Trace Carbon Monoxide Detection with a Cavity Ring-Down Spectrometer]

Autor: Bing, Chen, Ze-yi, Zhou, Peng, Kang, An-wen, Liu, Shui-rning, Hu
Rok vydání: 2015
Zdroj: Guang pu xue yu guang pu fen xi = Guang pu. 35(4)
ISSN: 1000-0593
Popis: A cavity ring-down spectrometer (CRDS) was built based on telecom distributed feedback (DFB) diode lasers. The ring down cavity was formed by mirrors of 99. 997% reflectivity with a separation of 130 cm, with an empty ring down time of about 150 µs. A minimum detectable absorption coefficient of 5 x 10(-12) cm(-1) was obtained by averaging about 1,000 recorded spectra. The ring down cavity is thermo-isolated, and used as an interferometer to calibrate the recorded spectrum. A feedback control scheme was applied to step scan the laser frequency, successively matching each of the longitudinal modes of the cavity. By measuring the CO contents in a standard gas sample, the quantitative capability of the CRDS instrument was demonstrated, and a CO detection limit of 4 ppb was achieved. The instrument was applied to monitor the CO concentration in ambient air.
Databáze: OpenAIRE