Autor: |
Mark C, Babin, Martin, DeWitt, Jascha A, Lau, Marissa L, Weichman, Jongjin B, Kim, Hongwei, Song, Hua, Guo, Daniel M, Neumark |
Rok vydání: |
2022 |
Zdroj: |
Nature chemistry. |
ISSN: |
1755-4349 |
Popis: |
The transition state of a chemical reaction is a dividing surface on the reaction potential energy surface (PES) between reactants and products and is thus of fundamental interest in understanding chemical reactivity. The transient nature of the transition state presents challenges to its experimental characterization. Transition-state spectroscopy experiments based on negative-ion photodetachment can provide a direct probe of this region of the PES, revealing the detailed vibrational structure associated with the transition state. Here we study the F + NH |
Databáze: |
OpenAIRE |
Externí odkaz: |
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