Transition metal chemistry in synthetically viable alkaline earth complexes M(Cp)

Autor: Bin, Huo, Rui, Sun, Bo, Jin, Lingfei, Hu, Jian-Hong, Bian, Xiao-Ling, Guan, Caixia, Yuan, Gang, Lu, Yan-Bo, Wu
Rok vydání: 2021
Zdroj: Chemical communications (Cambridge, England). 57(47)
ISSN: 1364-548X
Popis: We predicted the stable alkaline earth complexes M(Cp)3- (M = Ca, Sr, Ba; Cp = cyclopentadienyl), where the M centers were in their stable +2 oxidation state and mimicked the bonding behaviour of transition metals by participating in bonding with the π orbitals of Cp ligands using their d orbitals.
Databáze: OpenAIRE