| Autor: |
Sergey, Malinkin, Larisa, Penkova, Vadim A, Pavlenko, Matti, Haukka, Igor O, Fritsky |
| Rok vydání: |
2009 |
| Předmět: |
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| Zdroj: |
Acta Crystallographica Section E: Structure Reports |
| ISSN: |
1600-5368 |
| Popis: |
The title compound, [Cu(2)(C(7)H(6)N(2)O(3))Cl(2)(C(5)H(5)N)(4)]·C(3)H(8)O, is a binuclear pyrazolate complex, in which the two Cu(II) atoms have different coordination numbers and are connected by a bridging Cl atom. One Cu(II) atom has a distorted square-pyramidal coordination environment formed by two pyridine N atoms, one bridging Cl atom and an N,O-chelating pyrazolate ligand. The other Cu(II) atom adopts an octa-hedral geometry defined by two pyridine N atoms at the axial positions, two Cl atoms and the coordinated pyrazolate ligand in the equatorial plane. An O-H⋯O hydrogen bond connects the complex mol-ecules and propan-2-ol solvent mol-ecules into pairs. These pairs form columns along the a axis. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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