| Autor: |
Hayato, Tsuji, Iku, Tanaka, Kohei, Endo, Ken-Ichi, Yamagata, Masaharu, Nakamura, Eiichi, Nakamura |
| Rok vydání: |
2009 |
| Zdroj: |
Organic letters. 11(8) |
| ISSN: |
1523-7052 |
| Popis: |
A catalytic amount of In(NTf(2))(3) effects the inter- and intramolecular addition of a beta-ketoester to an alpha,omega-diyne to produce a 1,3-dimethylenecycloalkane derivative in a single step. This [1 + n] annulation reaction shows good functional group tolerance and allows the synthesis of five- to seven-membered carbo- and heterocyclic as well as spirocyclic structures in moderate to excellent yields. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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