| Autor: |
James A, Isaac, Aurore, Thibon-Pourret, Amélie, Durand, Christian, Philouze, Nicolas, Le Poul, Catherine, Belle |
| Rok vydání: |
2019 |
| Zdroj: |
Chemical communications (Cambridge, England). 55(84) |
| ISSN: |
1364-548X |
| Popis: |
The electrochemically generated CuIICuIII mixed-valence species promotes activation of strong aliphatic C-H bonds (i.e. toluene) at room temperature. The mechanistic pathway turns from stoichiometric to catalytic upon addition of base, hence demonstrating that such high-valence dicopper species can be key reactive intermediates in copper-based oxidative processes. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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