Lactide Lactone Chain Shuttling Copolymerization Mediated by an Aminobisphenolate Supported Aluminum Complex and Al(O

Autor: Julie, Meimoun, Choltirosn, Sutapin, Grégory, Stoclet, Audrey, Favrelle, Pascal, Roussel, Marc, Bria, Suwabun, Chirachanchai, Fanny, Bonnet, Philippe, Zinck
Rok vydání: 2021
Zdroj: Journal of the American Chemical Society. 143(50)
ISSN: 1520-5126
Popis: The chain shuttling ring-opening copolymerization of l-lactide with ε-caprolactone has been achieved using two aluminum catalysts presenting different selectivities and benzyl alcohol as chain transfer agent. A newly synthesized aminobisphenolate supported aluminum complex affords the synthesis of lactone rich poly(l-lactide
Databáze: OpenAIRE