Synthesis, solution and spectral studies of palladium(II) complexes with 2-hydroxyacetophenone N(3)-propylthiosemicarbazone. Crystal structure of a tripalladium complex

Autor:	Yadav, P. N., Demertzis, M. A., Kovala-Demertzi, D., Castineiras, A., West, D. X.
Jazyk:	angličtina
Rok vydání:	2002
Předmět:	crystal structures trinuclear triangulo palladium (ii) one-dimensional extended network n-4-substituted thiosemicarbazones antitumor-activity hydrogen platinum(ii) first organotin complex copper(ii) complexes in-vitro dissociation constants adducts 2-hydroxyacetophenone n(3) propylthiosemicarbazone
Popis:	The reactions of palladium(II) salts with 2-hydroxyacetophenone N(3)-propylthiosemicarbazone, H(2)Ap3Pr, are described. The synthesis and spectral characterization of a new triangular, trinuclear palladium(II) complex with the dianion, Ap3Pr(2-), are reported. The X-ray crystal structure determination of [Pd(Ap3Pr(2))](3).DMF shows it to contain a chair-form hexagon of alternating Pd and S atoms to form a molecular bowl. The spectrophotometric characterization of H(2)Ap3Pr is also reported. (C) 2002 Elsevier Science B.V. All rights reserved. Inorganica Chimica Acta
Databáze:	OpenAIRE
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